Worldwide, the main sources of greenhouse gases are: fuels combustion in electricity generation and fuels combustion in vehicles use.
Other very important sources are oil and gas production, livestock, deforestation and forest degradation, agricultural production of some grains, use of fertilizers, solid waste (mis)management, and water treatment.
But the relative importance and contribution of each of these activities varies by country, according to the type of infrastructure is has for electricity generation, or waste management. The industrialised countries prepare and publish emissions inventories every year. You may find them here: http://unfccc.int/national_reports/items/1408.php Look for "GHG Inventories".
Not all countries prepare inventories in an annual basis. Some have prepared one or two, just to have a rough idea of how much they emit and from which sources.
Given that combustion of fossil fuels is the main source of greenhouse gas emissions, the International Energy Agency (IEA) prepares and publishes its own estimate of emissions based on data on fuels production and trade provided by the country members to IEA. Look here for their statistics: http://www.iea.org/stats/index.asp
Also the Energy Information Administration (EIA) from the United Sates, prepares and publishes similar estimates, based on data collected by them. Look here: http://www.eia.doe.gov/environment.html
Other independent estimates are done by the World Resources Institute, a non-governmental organisation that works on different topics, including climate change: http://earthtrends.wri.org/searchable_db/index.php?theme=3
The other side of the coin is how the CO2 is captured and retained by natural means... that is part of the CO2 natural cycle. Here, the important part is that the oceans, the forested areas, and the soils play an important part. If they are degraded somehow, their natural ability to capture and retain CO2 diminishes. Some estimates on this regard are done by the International Geosphere-Biosphere Programme (IGBP) through the Global Carbon Project (GCP). They publish the "Carbon Budget", an estimate on how the natural capacity to deal with increasing emissions is changing. Look here: http://www.globalcarbonproject.org/carbonbudget/08/presentation.htm
Hope this helps